The 2-substituted derivatives of (4R)-4-hydroxycyclopent-2-enone (11) and (12), important intermediates in prostaglandin synthesis, are prepared from (4S)-3-chloro-4-(dimethyl-t-butylsilyloxy)cyclopent-2-enone (4) which is available in five steps from phenol.
M. Gill and R. W. Rickards, J. Chem. Soc., Chem. Commun., 1979, 121 DOI: 10.1039/C39790000121
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