The reaction of plasma-generated trifluoromethyl radicals with carbon tetraiodide leads to a mixture of perfluoroneopentane and perfluoro-t-butyl iodide in 97% total yield; bromobenzene reacts with trifluoromethyl radicals to give a 10–15% yield of trifluoromethylbenzene.
R. A. Jacob, L. L. Gerchman, T. J. Juhlke and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1979, 128 DOI: 10.1039/C39790000128
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