The sense of the contribution of polarizable allylic axial bonds to the π–π* Cotton effect of dienes is found to be determined by the chirality of the system which is defined by the direction of the transition moment and direction of the allylic bond.
J. Gawronski and K. Gawronska, J. Chem. Soc., Chem. Commun., 1980, 346 DOI: 10.1039/C39800000346
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