The insertion product, W2(CO)8[C9H14], of but-2-yne into the µ-alkylidene complex W2(CO)9[µ-CHCHCMe2] rearranges easily to the tungstole-tungsten derivative W2(CO)8[C9H14], possibly via a mechanism which involves α- and β-elimination reactions promoted by metal–metal bond rupture.
J. Levisalles, F. Rose-munch, H. Rudler, J. Daran and Y. Jeannin, J. Chem. Soc., Chem. Commun., 1981, 1057 DOI: 10.1039/C39810001057
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