Reaction of di-iodonitrosyl[tris(3,5-dimethylpyrazolyl)borato]-molybdenum with α,ω-alkanediols, 2-chloro-, and 2-methoxy-ethanol

Abstract

The complexes [Mo{HB(3,5-Me₂C₃HN₂)₃}(NO)l{O(CH₂)_nR}][R = OH, n= 2–6; R = Cl or OMe, n= 2] and [Mo{HB(3,5-Me₂C₃HN₂)₃}(NO){O(CH₂)_nOH}₂](n= 2) have been prepared by the reaction of [Mo{HB(3,5-Me₂C₃HN₂)₃}(NO)l₂] with the appropriate α,ω-alkanediol, 2-chloro- or 2-methoxy-ethanol. No evidence could be found for chelated complexes of the type [[graphic omitted]}].