The complex (TPP)FeIV : O (TPP = tetraphenylporphyrin) reacts in solution with an imidazole-bearing CuI complex to form a stable mixed-metal µ-oxo-species, [Fe3+–O–Cu2+]+, as a resting state model compound for the binuclear active site of cytochrome c oxidase.
R. J. Saxton, L. W. Olson and L. J. Wilson, J. Chem. Soc., Chem. Commun., 1982, 984 DOI: 10.1039/C39820000984
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