The reactions of oxygen, sulphur, and selenium with the complexes [(triphos)Co(η2CS2)] and [(triphos)Co(η2CS2Me)] BPH4[triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane] are described; these reactions provide evidence for the carbenoid nature of the metal–(η2-CS2)and metal–(η2-CS2Me) moieties.
C. Bianchini and A. Meli, J. Chem. Soc., Chem. Commun., 1983, 156 DOI: 10.1039/C39830000156
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