The silica in some biominerals has been investigated by electron microscopy and i.r. and n.m.r. spectroscopy and has been shown to be amorphous and to contain many Si–OH units.
S. Mann, C. C. Perry, R. J. P. Williams, C. A. Fyfe, G. C. Gobbi and G. J. Kennedy, J. Chem. Soc., Chem. Commun., 1983, 168 DOI: 10.1039/C39830000168
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