Acetylene reacts to form benzene on Pd(111) at ca. 200 K; photoelectron spectroscopy indicates that the reaction intermediate lies flat, and that competitive formation of ethylene involves an intermediate with perpendicular adsorption geometry.
W. T. Tysoe, G. L. Nyberg and R. M. Lambert, J. Chem. Soc., Chem. Commun., 1983, 623 DOI: 10.1039/C39830000623
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