Matrix isolation evidence form [(η5-C5H5)W(CO)2NO](1a) and its labelled analogues containing 13CO, C18O, or N18O indicates an intramolecular CO attack at the nitrogen of a NO ligand in the photochemical formation of a group 6 metal isocyanato-species.
R. B. Hitam, A. J. Rest, M. Herberhold and W. Kremnitz, J. Chem. Soc., Chem. Commun., 1984, 471 DOI: 10.1039/C39840000471
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