In reactions of oxiranes with sulphur nucleophiles under conditions in which kobs. is pH independent, aryloxiranes show none of the expected enhancement of reactivity; conformational restriction of orthogonal substitution accounts for the observations.
J. I. Lynas-Gray and C. J. M. Stirling, J. Chem. Soc., Chem. Commun., 1984, 483 DOI: 10.1039/C39840000483
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