In the presence of Lewis acids, protected homoallylic alcohols of high diastereoisomeric excesses (up to 89%) were obtaine by he addition of allyltrimethylsilane to chrial α-keto-amides derived from (S)-proline esters.
K. Soai and M. Ishizaki, J. Chem. Soc., Chem. Commun., 1984, 1016 DOI: 10.1039/C39840001016
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