The reaction of benzamidine wiht S3N3Cl3 yields 1-chloro-3,5-diphenyl-1,2,4,6-thiatriazine, whose molecular structure has been determined by X-ray crystallography; reduction of Ph2C2N3SCl with triphenylantimony yields the radical species (Ph2C2N3S)· characterized by its e.s.r. spectrum.
A. W. Cordes, P. J. Hayes, P. D. Josephy, H. Koenig, R. T. Oakley and W. T. Pennington, J. Chem. Soc., Chem. Commun., 1984, 1021 DOI: 10.1039/C39840001021
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