Issue 22, 1984

N.m.r. studies of phenyl-substituted group 4 anions. Ion-pairing and charge delocalization vs. π-polarization effects

Abstract

The n.m.r. chemical shifts of phenyl-substituted silyl, germyl, stannyl, and plumbyl anions show that the remote phenyl carbon positions are mainly affected by π-polarizing effects and that conjugative effects are unimportant in these anionic systems.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1476-1477

N.m.r. studies of phenyl-substituted group 4 anions. Ion-pairing and charge delocalization vs. π-polarization effects

E. Buncel, T. K. Venkatachalam, U. Edlund and B. Eliasson, J. Chem. Soc., Chem. Commun., 1984, 1476 DOI: 10.1039/C39840001476

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