Issue 22, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

1,3-Methyl migration from germanium to silicon in reactions of (Me3Si)2(Me3Ge)C(SiMe2Br) with silver salts

Colin Eaborn  and  Anil K. Saxena  

Abstract

the germanium halide (Me3Si)3C(GeMe2Cl) reacts with silver salts AgY to give (Me3Si)3C(GeMe2Y), whereas the related silicon halide (Me3Si)2(Me3Ge)C(SiMe2Br) gives a mixture of the rearranged and unrearranged products, (Me3Si)3C(GeMe2Y) and (Me3Si)2(Me3Ge)C(SiMe2Y).

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Article information

DOI
https://doi.org/10.1039/C39840001482
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1482-1483

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1,3-Methyl migration from germanium to silicon in reactions of (Me3Si)2(Me3Ge)C(SiMe2Br) with silver salts

C. Eaborn and A. K. Saxena, J. Chem. Soc., Chem. Commun., 1984, 1482 DOI: 10.1039/C39840001482

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