The first copper(I) dimer having only a single phenolate bridge has been prepared and structurally characterized; its irreversible oxidation suggests the importance of site isolation in type III copper proteins.
T. N. Sorrell and A. S. Borovik, J. Chem. Soc., Chem. Commun., 1984, 1489 DOI: 10.1039/C39840001489
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