Reaction of the octaethylporphyrinatobis(triphenylarsine)ruthenium(III) cation with CO generates the carbonyl(triphenylarsine)ruthenium(II) porphyrin π-cation radical species viaan intramolecular electron transfer; the process is quantitatively reversible.
M. H. Barley, D. Dolphin and B. R. James, J. Chem. Soc., Chem. Commun., 1984, 1499 DOI: 10.1039/C39840001499
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