Issue 0, 1985
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Reactions of tetrafluoroethene oligomers. Part 3. Some reactions of tetrafluoroethene hexamer with nitrogenous bases

Paul L. Coe,   Alan Sellars  and  John Colin Tatlow  

Abstract

Tetrafluoroethene (TFE) hexamer (1)[Rf(Rf′)C[double bond, length as m-dash]CF2, Rf= CF3(C2F5)2C-, Rf′= CF3(C2F5)CF-] reacted with ammonia to give RfCH2CN (11) and with primary amines RNH2, (R = Et, NH2, Ph, CH2CH2OH) to give the corresponding ketenimine Rf(Rf′)C[double bond, length as m-dash]C[double bond, length as m-dash]NR (14)–(17). With 1,2-diaminoethane the dihydroimidazole C2F5(CF3)C[double bond, length as m-dash]C(Rf) [graphic omitted]H (20) was formed. With secondary amines (dimethylamine and piperidine) enamines of the type Rf(Rf′)C[double bond, length as m-dash]CFNMe2(18) and Rf(Rf′)C[double bond, length as m-dash]CF[graphic omitted]H2, (21) were obtained. These latter products, on being heated, afforded respectively the ketenimines Rf(Rf′)C[double bond, length as m-dash]C[double bond, length as m-dash]NMe (19), and Rf(Rf′)C[double bond, length as m-dash]C[double bond, length as m-dash]N[CH2]3CH[double bond, length as m-dash]CH2(12), Rf(Rf′)C[double bond, length as m-dash]C[double bond, length as m-dash]N[CH2]5F (23).

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Article information

DOI
https://doi.org/10.1039/P19850002185
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 2185-2189

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Reactions of tetrafluoroethene oligomers. Part 3. Some reactions of tetrafluoroethene hexamer with nitrogenous bases

P. L. Coe, A. Sellars and J. C. Tatlow, J. Chem. Soc., Perkin Trans. 1, 1985, 2185 DOI: 10.1039/P19850002185

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