Correlations have been observed between the 31P n.m.r. chemical shifts of crystalline inorganic phosphates and the bond strengths at the phosphate oxygen atoms; these provide a basis for structural studies and for peak assignment in phosphates that give more than one resonance.
A. K. Cheetham, N. J. Clayden, C. M. Dobson and R. J. B. Jakeman, J. Chem. Soc., Chem. Commun., 1986, 195 DOI: 10.1039/C39860000195
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