Based on the analysis of the unimolecular reactions of metastable cluster ions from fast atom bombardment mass spectrometry, the relative proton affinities of four common amino acids are found to be in the order: Arg>His>Lys>Trp.
G. Bojesen, J. Chem. Soc., Chem. Commun., 1986, 244 DOI: 10.1039/C39860000244
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