Issue 3, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

The aminocarbyne ligand CNH2: metal-centred synthesis from a cyanosilane, preparation and X-ray structure of trans-[ReCl(CNH2)(Ph2PCH2CH2PPh2)2]BF4

Armando J. L. Pombeiro,   David L. Hughes,   Christopher J. Pickett  and  Raymond L. Richards  

Abstract

Treatment of trans-[ReCl(N2)(dppe)2](dppe = Ph2PCH2CH2PPh2) with trimethylsilyl cyanide affords trans-[ReCl(CNSiMe3)(dppe)2](1) which, on reaction with MeOH or HBF4, gives trans-[ReCl(CNH)(dppe)2](2) and trans-[ReCl(CNH2)(dppe)2]BF4(3), respectively; the X-ray structure of complex (3) has been determined.

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Article information

DOI
https://doi.org/10.1039/C39860000246
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 246-247

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The aminocarbyne ligand CNH2: metal-centred synthesis from a cyanosilane, preparation and X-ray structure of trans-[ReCl(CNH2)(Ph2PCH2CH2PPh2)2]BF4

A. J. L. Pombeiro, D. L. Hughes, C. J. Pickett and R. L. Richards, J. Chem. Soc., Chem. Commun., 1986, 246 DOI: 10.1039/C39860000246

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