The first carbonium ion rearrangement of the [3.3.3]propellane ring system to the tricyclo[4.3.2.01,5]undecane and tricyclo[6.3.0.01,5]undecane skeletons has been observed and extended to the total synthesis of the biologically active compound decarboxyquadrone.
G. Mehta, K. Pramod and D. Subrahmanyam, J. Chem. Soc., Chem. Commun., 1986, 247 DOI: 10.1039/C39860000247
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