Excitation of CdS in the presence of 7,8-diphenylbicyclo[4.2.0]oct-7-ene gave the cation radical of the latter which underwent a reversible [1,3] sigmatropic hydrogen shift; this is the first such observation in a radical cation.
P. de Mayo and G. Wenska, J. Chem. Soc., Chem. Commun., 1986, 1626 DOI: 10.1039/C39860001626
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