In order to provide additional insight into the mode of action of the trichothecene mycotoxins, one of the first semi-synthetic trichothecene epi-epoxides (8) has been prepared; in dramatic contrast to its natural isomer (9), this compound proved to be devoid of significant biological activity.
E. W. Colvin and S. Cameron, J. Chem. Soc., Chem. Commun., 1986, 1642 DOI: 10.1039/C39860001642
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