Iodine-induced cyclization of γ,δ-unsaturated secondary thioamides proceeds regio- and chemo-selectively, providing, after elaboration, 2-aminothiophenes.
H. Takahata, K. Moriyama, M. Maruyama and T. Yamazaki, J. Chem. Soc., Chem. Commun., 1986, 1671 DOI: 10.1039/C39860001671
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