Thermolysis of the germaphosphene (1) affords nearly quantitatively the germaphosphetene (4), which is the first stable four-membered heterocycle with a Ge–P–C linkage; its structure has been determined by X-ray crystallography.
M. Andrianarison, C. Couret, J. Declercq, A. Dubourg, J. Escudie and J. Satge, J. Chem. Soc., Chem. Commun., 1987, 921 DOI: 10.1039/C39870000921
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