Benzene is directly activated by palladium(II) acetate-dialkyl sulphide systems at 70 °C to afford acetato-bridged diphenyltripalladium(II) complexes [(R2S)PhPd(µ-MeCO2)2Pd(µ-MeCO2)2PdPh(SR2)], which are regarded as intermediate species in the catalytic arylation of alkenes and carbonylation of arenes by palladium(II) acetate.
Y. Fuchita, K. Hiraki, Y. Kamogawa and M. Suenaga, J. Chem. Soc., Chem. Commun., 1987, 941 DOI: 10.1039/C39870000941
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