[(thf)Br2Ga]3As (thf = tetrahydrofuran), isolated from the products of the reaction of (Me3Si)3As with GaBr3, has been shown by X-ray crystallographic analysis to be the first example of a compound containing a single Ga3As unit.
R. L. Wells, S. Shafieezad, A. T. McPhail and C. G. Pitt, J. Chem. Soc., Chem. Commun., 1987, 1823 DOI: 10.1039/C39870001823
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