Asymmetric synthesis of milbemycin and avermectin spiroacetals
Abstract
Spiroacetals (16) and (29) have been synthesized from dimethyl (S)-malate (9)via convergent routes which use chiral boron reagents to control stereochemistry.
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J. Chem. Soc., Chem. Commun., 1987, 1826-1828
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Asymmetric synthesis of milbemycin and avermectin spiroacetals
E. Merifield, P. G. Steel and E. J. Thomas, J. Chem. Soc., Chem. Commun., 1987, 1826 DOI: 10.1039/C39870001826
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