Issue 24, 1987

Preparation and crystal structure of the addition compound MeLi·U[OCH(CMe3)2]4, a compound with a uranium to carbon σ-bond

Abstract

Reaction of MeLi and U[OCH(CMe3)2]4 gives the addition compound, LiU(Me)[OCH(CMe3)2]4 which in the solid state has a geometry based upon square pyramidal uranium with the apical site occupied by a methyl group and the four basal sites being occupied by oxygen atoms of the alkoxide ligand, two of which form bridges to the lithium atom.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1846-1847

Preparation and crystal structure of the addition compound MeLi·U[OCH(CMe3)2]4, a compound with a uranium to carbon σ-bond

J. L. Stewart and R. A. Andersen, J. Chem. Soc., Chem. Commun., 1987, 1846 DOI: 10.1039/C39870001846

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