Alcohols with up to 19% enantiomeric excess were obtained on hydroboration/oxidation of representative prochiral olefins using N-isobornyl-N-methylaniline–borane or N-benzyl-N-isopropyl-α-methylbenzylamine–borane indicating that the Lewis base is present in the hydroboration transition state.
C. Narayana and M. Periasamy, J. Chem. Soc., Chem. Commun., 1987, 1857 DOI: 10.1039/C39870001857
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