The total synthesis of (–)-litsenolides C1 and C2 from D-glucose in 12% overall yield is described in which the α-alkylidene double-bond is formed by a Wittig reaction of a C-2 oxocarbohydrate derivative.
W. W. Wood and G. M. Watson, J. Chem. Soc., Perkin Trans. 1, 1987, 2681 DOI: 10.1039/P19870002681
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