Synthesis of the left-hand portion [(±)-(13)] of tetronomycin (1)via an aldol reaction of methyl γ-methylene-β-tetronate (12) with aldehyde (11) prepared from 3-methoxy-5-methylbenzoic acid is reported.
K. Hori, K. Nomura, S. Mori and E. Yoshii, J. Chem. Soc., Chem. Commun., 1989, 712 DOI: 10.1039/C39890000712
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