Insertion of Pri2NBCI2 into Li2[7-Me3N-nido-7-CB10H10] induces removal of a methyl group from the trimethylamine substituent, methylene insertion into the exo-polyhedral B-N bond and protonation of the diisopropylamino group to give 1-Me2N-2-Pri2N(H)CH2-closo-1-CB11H10, which has been characterised by multinuclear NMR and X-ray crystallography.
F. S. Mair, A. Martin, J. H. Morris, G. S. Peters and M. D. Spicer, J. Chem. Soc., Chem. Commun., 1993, 1058 DOI: 10.1039/C39930001058
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