The catalytic Fries rearrangement of acyloxy naphthalenes proceeds smoothly using a small amount of scandium trifluoromethanesulfonate (5 mol%) to afford the corresponding hydroxynaphthyl ketones in high yields.
S. Kobayashi, M. Moriwaki and I. Hachiya, J. Chem. Soc., Chem. Commun., 1995, 1527 DOI: 10.1039/C39950001527
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