Pre-reactive complexes B ⋯ ClF, where B is ethyne or ethene, of C2v symmetry have been isolated in mixtures of B and ClF by using a fast-mixing nozzle in a pulsed-nozzle, Fourier-transform microwave spectrometer and characterised by their rotational spectra.
H. I. Bloemink, K. Hinds, A. C. Legon and J. H. Holloway, J. Chem. Soc., Chem. Commun., 1995, 1833 DOI: 10.1039/C39950001833
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