Template synthesis and X-ray crystal structure of a trinuclear complex with four- and five-coordinate silver(i) centres
Abstract
Single-crystal X-ray analysis of the trinuclear complex
[Ag
3
L
2
][CF
3
SO
3
]
3
[L
=
{(o-Ph
2
C
6
H
4
)CH=NCH
2
CH
2
}
3
N], synthesized by interaction of
Ag(CF
3
SO
3
),
N(CH
2
CH
2
NH
2
)
3
and
o-Ph
2
PC
6
H
4
(CHO) in 3:2:6 molar
ratio in ethanol, shows that the complex has approximate
C
2
symmetry and is composed of a four- and
two five-coordinate silver(i) centres.
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