Phosphorus monoxide as a terminal ligand
Abstract
Dimethyldioxirane oxidation of phosphide PMo[N(R)Ar]
3
[R =
C(CD
3
)
2
Me, Ar =
C
6
H
3
Me
2
-3,5] efficiently provides
(OP)Mo[N(R)Ar]
3
, a complex shown by X-ray crystallography to
contain a terminal phosphorus monoxide ligand, and which reacts with
dimethylzirconocene to give addition of a Zr–Me bond across the
phosphoryl moiety.
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