Carbon monoxide–phosphaalkyne coupling and C–Hactivation of an N–Me group in the4e-η2-phosphaalkyne complex[WF(C6H4CH2NMeCH2CH2NMe2)(CO)(η2-PCBut)].Crystal and molecular structure of[WF{CH2N(CH2Ph)CH2CH2NMe2}(CO){η4-PCBut(CO)CButP}]

Maria Helena A. Benvenutti; Peter B. Hitchcock; Jaqueline L. Kiplinger; John F. Nixon; Thomas G. Richmond

doi:10.1039/A703303F

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Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η²-phosphaalkyne complex [WF(C₆H₄CH₂NMeCH₂CH₂NMe₂)(CO)(η²-PCBu^t)]. Crystal and molecular structure of [WF{CH₂N(CH₂Ph)CH₂CH₂NMe ₂}(CO){η⁴-PCBu^t(CO)CBu ^tP}]

Maria Helena A. Benvenutti, Peter B. Hitchcock, Jaqueline L. Kiplinger, John F. Nixon and Thomas G. Richmond

Abstract

An unusual series of reactions involving an intermediate 4e η ² -phosphaalkyne tungsten complex is described.

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DOI: https://doi.org/10.1039/A703303F
Article type: Paper

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Chem. Commun., 1997, 1539-1540

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Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η²-phosphaalkyne complex [WF(C₆H₄CH₂NMeCH₂CH₂NMe₂)(CO)(η²-PCBu^t)]. Crystal and molecular structure of [WF{CH₂N(CH₂Ph)CH₂CH₂NMe ₂}(CO){η⁴-PCBu^t(CO)CBu ^tP}]

M. Helena A. Benvenutti, P. B. Hitchcock, J. L. Kiplinger, J. F. Nixon and T. G. Richmond, Chem. Commun., 1997, 1539 DOI: 10.1039/A703303F

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Chemical Communications

Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η²-phosphaalkyne complex [WF(C₆H₄CH₂NMeCH₂CH₂NMe₂)(CO)(η²-PCBu^t)]. Crystal and molecular structure of [WF{CH₂N(CH₂Ph)CH₂CH₂NMe ₂}(CO){η⁴-PCBu^t(CO)CBu ^tP}]

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Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η²-phosphaalkyne complex [WF(C₆H₄CH₂NMeCH₂CH₂NMe₂)(CO)(η²-PCBu^t)]. Crystal and molecular structure of [WF{CH₂N(CH₂Ph)CH₂CH₂NMe ₂}(CO){η⁴-PCBu^t(CO)CBu ^tP}]

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