Modhephene has been synthesized in 11 steps and 21% overall yield from cyclopentadiene, by a stereoselective route that features a photocycloaddition–fragmentation sequence for the construction of the diquinane core.
C. A. Dvorak and V. H. Rawal, Chem. Commun., 1997, 2381 DOI: 10.1039/A704260D
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