Three-component reactions of aldehydes, amines and allyltributylstannane proceeded smoothly in water without using any organic solvents, in the presence of a small amount of scandium trifluoromethanesulfonate [Sc(OTf)3] and sodium dodecylsulfate (SDS), to afford the corresponding homoallylic amines in high yields.
S. Kobayashi, Chem. Commun., 1998, 19 DOI: 10.1039/A706498E
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