4-Benzyloxy-4′-(2,3-dihydroxypropyloxy)biphenyls with lateral methyl substituents are a novel class of amphiphilic mesogens displaying thermotropic and lyotropic smectic and columnar mesophases due to microsegregation of hydrophilic regions from all-aromatic segments in the absence of a flexible alkyl chain.
M. Kölbel, C. Tschierske and S. Diele, Chem. Commun., 1998, 1511 DOI: 10.1039/A802540A
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