Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9′-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by H-bonding in CDCl3; the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.
D. K. Smith and F. Diederich, Chem. Commun., 1998, 2501 DOI: 10.1039/A806596I
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