Intermolecular-hydrogen bonding interactions have been shown to result in a shortening of the copper–copper distance by 0.274 Å to 2.5526(5) Å in [Cu2{µ-SC(NH2)2}2{SC(NH2)2}4]2+ in comparison to three structures of the same cation in the absence of significant intermolecular interactions.
K. Johnson and J. W. Steed, J. Chem. Soc., Dalton Trans., 1998, 2601 DOI: 10.1039/A803708F
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