On reaction with the dimolybdenum alkyne complex [Mo2{µ-C2(CO2Me)2}(CO)4(η-C5H5)2], dialkyl trithiocarbonates (RS)2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
S were dismantled into sulfido (µ-S), thiolate (µ-SR) and CSR fragments; remarkably the last of these inserts into the middle of the alkyne to produce a dimetalla-allyl species with a µ-C(CO2Me)C(SR)C(CO2Me) ligand.
H. Adams, C. Allott, M. N. Bancroft and M. J. Morris, J. Chem. Soc., Dalton Trans., 1998, 2607 DOI: 10.1039/A804138E
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