Reported for the first time is the stereoselective synthesis of (Z)-vinyl formates, which involves in-plane bimolecular nucleophilic vinylic substitutions of (E)-β-alkylvinyl(phenyl)iodonium tetrafluoroborates with formamides.
M. Ochiai, S. Yamamoto and K. Sato, Chem. Commun., 1999, 1363 DOI: 10.1039/A904220B
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