Issue 22, 1999
From the journal:

Chemical Communications

Synthesis and structures of a triply-fused incomplete-cubane cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 and a 2D polymer [(η5-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine)

Jian-Ping Lang,   Hiroyuki Kawaguchi  and  Kazuyuki Tatsumi  

Abstract

The reaction of PPh4[(η5-C5Me5)WS3] with 3 equiv. of [Cu(MeCN)4]PF6 in MeCN yielded an unusual high nuclearity W/Cu/S cluster [{(η5-C5Me5)WS3}3Cu7- (MeCN)9](PF6)4 1, which in turn gave rise to a 2D polymer [(η5-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 2 upon treatment with pyrazine in MeCN in the presence of LiCl.

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Article information

DOI
https://doi.org/10.1039/A906081B
Article type
Paper

Chem. Commun., 1999, 2315-2316

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Synthesis and structures of a triply-fused incomplete-cubane cluster [{(η5-C5Me5)WS3}3Cu7(MeCN)9](PF6)4 and a 2D polymer [(η5-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine)

J. Lang, H. Kawaguchi and K. Tatsumi, Chem. Commun., 1999, 2315 DOI: 10.1039/A906081B

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