Insertion of glycosylidene carbenes into a B–C bond of BEt3 leads to unstable glycosyl boranes, while insertion into a B–C bond of borinic esters yields stable anomeric glycosyl borinates.
A. Vasella, W. Wenger and T. Rajamannar, Chem. Commun., 1999, 2215 DOI: 10.1039/A906400A
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