New copper(I) complexes [CuI3(mesO–)]2+ (3) and [CuI3- (mesOH)]3+ (4) have been generated from a phenol-containing trinucleating ligand, mesOH; reactions with O2 reflect the unsymmetrical ligand environment, and lead to peroxo and/or hydroperoxo cluster complexes, including those with mixed-valent copper ion centers.
K. D. Karlin, Q. Gan and Z. Tyeklár, Chem. Commun., 1999, 2295 DOI: 10.1039/A906830I
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