A highly enantioselective addition reaction of a chiral allylsilane to an activated N-acylisoquinolinium ion
Abstract
The addition reactions of a chiral allylsilane to activated N-acylisoquinolinium ions proceeded in a highly enantioselective manner (more than 90%) to afford homochiral 1-allyl-1,2-dihydroisoquinolines in good yields.